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991.
Temperature-sensitive hydrogels are attracting increasing attention for controlled drug delivery. However, achieving high drug loadings and sustained drug release remains challenging. Herein, we describe the successful synthesis of a series of novel temperature-sensitive poly(N-isopropylacrylamide) (PNIPA)/mesoporous silica nanoparticles (MSN) hydrogels by physical crosslinking of NIPA with MSN. The external and internal structures, temperature sensitivity, drug-loading capacity, and blood compatibility of the PNIPA/MSN composite hydrogels are studied. Results show that MSN addition improved the network structure and adjusted the size of the hole, MSN could also act as drug carrier, thereby enhancing the drug loading capacity. The composite hydrogels underwent a phase transition at 33.7 °C (at the lower critical solution temperature). The hemolysis rate of the composite hydrogels was less than 1%, thus they can be classified as a nonhemolytic materials with good biocompatibility. The composite hydrogels reported here thus have great potential in drug transport and temperature-activated drug release. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 48391. 相似文献
992.
The uniaxial tension experiments are performed on thermoplastic polyurethane to investigate its mechanical behaviors and related potential mechanisms, and the loading strain rate is designing to be wide ranging from 0.0001 to 1 s−1. It is found that the polyurethane presents an obvious rate-dependence, and the stress strain curves share distinct strain hardening characteristics under the investigated strain rates. Furthermore, the strain hardening ratios are sharing nearly same trends and appear to be influenced by both strain rate and the induced adiabatic heating. Besides, the ratio is also strain-dependent on previous loading history. Then, a two-dimension unit cell model is built to investigate potential equivalent mechanisms, of which the hard phase as inclusion is equivalent with crystallization zone, crosslinking sites, and so forth. The simulation results facilitate to explain the distinct strain hardening ratios, even for the matrix from the extrapolated curves under super-low strain rate loading. Finally, the analogic mechanisms of equivalent hard inclusions are proposed, which can reasonably explain the strain rate- and strain-dependence characteristics of polyurethane mechanical behaviors. 相似文献
993.
994.
Hanyue Deng Jun Liao Junyu Piao Yong Zhang Simin He Qing Zhou Yi Li Long Zhang 《应用聚合物科学杂志》2020,137(38):49137
Photothermal effect has been widely used in many areas such as cancer therapy, photothermal energy harvesting, and laser ignition. However, exploring reliable and efficient free-standing energy converter for enhancing the photothermal performance is still a challenge. Herein, free-standing membrane based on two-dimensional MXene (Ti3C2) nanosheets and polytetrafluoroethylene (PTFE) was fabricated and characterized by X-ray diffraction, scanning electron microscopy and differential scanning calorimetry, which demonstrated a drastic temperature rise by laser irradiation and was further used as energy converter for enhancing the photothermal performance of laser ignition. Furthermore, the initiating power of the laser initiator can be largely reduced by adding a thin layer of MXene/PTFE membrane above the B/KNO3 cylinder. This work can give great promise for MXene-based membranes as the laser energy converter for reducing the initiating energy and promote the development of laser initiators with low initiating energy. 相似文献
995.
Xiao-Fang Song Jiang-Tao Qin Ting-Ting Li Guo Liu Xiang-Xiang Xia Yue-Sheng Li Yi Liu 《应用聚合物科学杂志》2020,137(13):48516
Enriched selective adsorption-photocatalytic activity of Poly (vinyl alcohol)/Polyaniline/TiO2 (PVA/PANI/TiO2, noted as PAT) recyclable hydrogel photocatalyst with 3D structures were prepared by self-assembling and electron beam radiation crosslingking method. TiO2 nanoparticles were successfully introduced into the 3D matrix of the PVA/PANI hydrogel and manifested by FTIR, TG, XRD, XPS, and SEM-EDS. The microstructure of PAT was characterized further by SEM, TEM, and BET. The highly selective adsorption-photocatalytic activity of PAT was tested by the degradation of cationic or anionic dye and reduction of heavy metal ion in a closed and flow system under UV light irradiation. The results showed that PAT had a highest selective adsorption-photocatalytic performance at the appropriate content of PVA (10 wt %), TiO2 (15 wt %) and suitable radiation dose (50 kGy), which could be attributed to the synergistic effect of excellent selective adsorption and effective photocatalytic degradation. The mechanism of selective adsorption-photocatalytic on PAT was revealed synchronously in this study. Particularly, the novel PAT photocatalyst with 3D network structure also affords ease of separation and recycling, which is beneficial to water purification in a flow system. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 48516. 相似文献
996.
997.
介绍国内外废旧轮胎综合利用传统方式和新模式以及发展方向。废旧轮胎综合利用的传统方式主要包括轮胎翻新、热能利用、热裂解、制备再生橡胶、制备胶粒和胶粉。结合有代表性的企业重点介绍了从废旧轮胎到胶粒、胶粉应用,从废旧轮胎到改性胶粉应用,从废旧轮胎到混炼胶、新轮胎或橡胶、橡塑制品全产业链闭合生态圈新模式,针对我国废旧轮胎高值化综合利用存在的循环利用率低,管理体系欠缺,政策立法不够全面等问题,提出应建立健全法律法规和回收体系,构建循环利用产品标准及准入机制,加快技术与综合利用模式的创新。 相似文献
998.
Isocyanate and amine solution are microencapsulated, respectively, via in situ polymerization to realize the self-healing function in epoxy matrix. First, the isophorone diisocyanate (IPDI) microcapsules prepared with different core/shell ratios, emulsifier dosages and emulsification rates are characterized by field emission scanning electron microscope (FE-SEM). They exhibit integral spherical shape when the core/shell ratio is 3:1 and emulsifier concentration is 2.52 wt %, and the diameter of IPDI microcapsules ranged from 2.66 μm to 11.25 μm is manufactured by adjusting emulsification rate over the range of 3000–9000 rpm. Besides, during the microencapsulation of polyaspartic acid ester (PAE), urea, tung oil, as well as aqueous isocyanate are proposed to improve the stability of PAE emulsion. SEM and FTIR results reveal that aqueous isocyanate can react with partial PAE and form polyurea (PU) layer to take protection effectively. Further, IPDI-PAE dual microcapsules are incorporated into epoxy coatings, the self-healing and anticorrosion performance of coatings with various amounts of microcapsules are investigated systematically. It was found that the degree of repair and anticorrosion are increased with increasing microcapsules loading, and the appropriate amount of microcapsules addition is 15 wt %, which corresponding to 93% repair efficiency. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 48478. 相似文献
999.
0前言环境污染问题愈来被人们所重视,降低成本、提高生产质量也一直是企业发展的关键因素,测量烟囱烟气含量的气体分析仪能为生产提供更为准确的判断,得到广泛应用。其在水泥生产行业中的作用是对窑尾烟室或分解炉中的氧气、一氧化碳、氮化物以及二氧化硫的含量进行实时监测,以保证回转窑中的水泥正常煅烧。 相似文献
1000.
从水泥强度偏差较大的两起典型案例的处理入手,梳理影响水泥强度检测数据较大偏差各种因素,提出应对不同试验室水泥强度较大偏差的“一查、二看、三比较、四操作”的四步法,以便类似问题能够快速查找到原因,有助于不同试验室间水泥强度偏差较大问题得到及时有效解决。 相似文献